Bell Ian H, Wronski Jorrit, Quoilin Sylvain, Lemort Vincent
Energy Systems Research Unit, University of Liège , Liège, Belgium.
Department of Mechanical Engineering, Technical University of Denmark , Kongens Lyngby, Denmark.
Ind Eng Chem Res. 2014 Feb 12;53(6):2498-2508. doi: 10.1021/ie4033999. Epub 2014 Jan 13.
Over the last few decades, researchers have developed a number of empirical and theoretical models for the correlation and prediction of the thermophysical properties of pure fluids and mixtures treated as pseudo-pure fluids. In this paper, a survey of all the state-of-the-art formulations of thermophysical properties is presented. The most-accurate thermodynamic properties are obtained from multiparameter Helmholtz-energy-explicit-type formulations. For the transport properties, a wider range of methods has been employed, including the extended corresponding states method. All of the thermophysical property correlations described here have been implemented into CoolProp, an open-source thermophysical property library. This library is written in C++, with wrappers available for the majority of programming languages and platforms of technical interest. As of publication, 110 pure and pseudo-pure fluids are included in the library, as well as properties of 40 incompressible fluids and humid air. The source code for the CoolProp library is included as an electronic annex.
在过去几十年里，研究人员针对纯流体以及被视为拟纯流体的混合物的热物理性质的关联和预测，开发了许多经验模型和理论模型。本文对热物理性质的所有最新公式进行了综述。最精确的热力学性质是通过多参数亥姆霍兹能量显式类型的公式获得的。对于输运性质，采用了更广泛的方法，包括扩展对应态方法。这里描述的所有热物理性质关联式都已被纳入CoolProp，一个开源的热物理性质库。该库用C++编写，有适用于大多数具有技术意义的编程语言和平台的包装器。截至发表时，该库包含110种纯流体和拟纯流体，以及40种不可压缩流体和湿空气的性质。CoolProp库的源代码作为电子附件包含在内。
