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碳基质尺寸对高性能对称钠离子电池 Na3V2(PO4)3 纳米颗粒电化学性能的影响。

Effect of carbon matrix dimensions on the electrochemical properties of Na3V2(PO4)3 nanograins for high-performance symmetric sodium-ion batteries.

机构信息

State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, WUT-Harvard Joint Nano Key Laboratory, Wuhan University of Technology, Wuhan, 430070, P. R. China.

出版信息

Adv Mater. 2014 Jun 4;26(21):3545-53. doi: 10.1002/adma.201305522. Epub 2014 Mar 14.

DOI:10.1002/adma.201305522
PMID:24633680
Abstract

Na3V2(PO4)3 nanograins dispersed in different carbon matrices are rationally synthesized and systematically characterized. The acetylene carbon matrix provides the best conductive networks for electrons and sodium ions, which endows Na3V2(PO4)3 stable cyclability and high rate performance. The Na3V2 (PO4)3 -based symmetric sodium-ion batteries show outstanding electrochemical performance, which is promising for large-scale and low-cost energy storage applications.

摘要

Na3V2(PO4)3 纳米颗粒分散在不同的碳基质中被合理合成并进行了系统的表征。乙炔碳基质为电子和钠离子提供了最佳的导电网络，使 Na3V2(PO4)3 具有稳定的循环性能和高倍率性能。基于 Na3V2(PO4)3 的对称钠离子电池表现出优异的电化学性能，有望应用于大规模和低成本的储能领域。

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