Centro Singular de Investigación en Química Biológica y Materiales Moleculares (CIQUS) and Departamento de Química Orgánica, Universidade de Santiago de Compostela, C/ Jenaro de la Fuente, s/n, 15782, Santiago de Compostela, Spain.
Chem Soc Rev. 2014 May 7;43(9):2904-15. doi: 10.1039/c4cs00024b. Epub 2014 Mar 18.
This feature review describes the development of catalytic [4+2] and [4+3] cycloadditions of allenes, as efficient and practical methodologies for assembling six and seven-membered cyclic systems. The different methodologies have been classified depending on the type of key reactive intermediate that was proposed in the catalytic cycle.
本篇综述介绍了丙二烯的催化 [4+2] 和 [4+3] 环加成反应的发展，这些反应是构建六元和七元环体系的有效且实用的方法。不同的方法学根据在催化循环中提出的关键反应中间体的类型进行了分类。
