Rh 催化的氧化 C-H 活化/环化反应：使用分子氧作为唯一氧化剂将苯胺转化为吲哚。
Rh-catalyzed oxidative C-H activation/annulation: converting anilines to indoles using molecular oxygen as the sole oxidant.
机构信息
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000, China.
出版信息
Chem Commun (Camb). 2014 Apr 28;50(33):4331-4. doi: 10.1039/c3cc49751h.
PMID:24643726
Abstract
A practical and efficient Rh(III)-catalyzed aerobic C-H activation has been developed for the facile synthesis of a broad range of indoles from simple anilines and alkynes. The protocol could be conducted under mild conditions and used environmentally friendly oxygen as the sole clear oxidant.
摘要
已开发出一种实用且高效的 Rh(III)-催化有氧 C-H 活化反应，可从简单苯胺和炔烃中轻松合成广泛的吲哚。该反应条件温和，可使用环保的氧气作为唯一的氧化剂。
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