使用空气作为唯一氧化剂，铑（III）催化的对五氟芳基苯甲酰胺的C-H烯基化反应。
Rh(iii)-catalyzed C-H olefination of -pentafluoroaryl benzamides using air as the sole oxidant.
作者信息
Lu Yi, Wang Huai-Wei, Spangler Jillian E, Chen Kai, Cui Pei-Pei, Zhao Yue, Sun Wei-Yin, Yu Jin-Quan
机构信息
Coordination Chemistry Institute , State Key Laboratory of Coordination Chemistry , School of Chemistry and Chemical Engineering , Nanjing National Laboratory of Microstructures , Collaborative Innovation Center of Advanced Microstructures , Nanjing University , Nanjing 210093 , China . Email:
Department of Chemistry , The Scripps Research Institute , 10550 N. Torrey Pines Road , La Jolla , California 92037 , USA . Email:
出版信息
Chem Sci. 2015 Mar 1;6(3):1923-1927. doi: 10.1039/c4sc03350g. Epub 2015 Jan 8.
The oxidative olefination of a broad array of arenes and heteroarenes with a variety of activated and unactivated olefins has be achieved a rhodium(iii)-catalyzed C-H activation reaction. The use of an -pentafluorophenyl benzamide directing group is crucial for achieving catalytic turnovers in the presence of air as the sole oxidant without using a co-oxidant.
通过铑（III）催化的C-H活化反应，已实现了多种芳烃和杂芳烃与各种活化和未活化烯烃的氧化烯基化反应。在仅以空气作为唯一氧化剂且不使用共氧化剂的情况下，使用对五氟苯基苯甲酰胺导向基团对于实现催化周转至关重要。
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