Graduate School of Pharmaceutical Sciences, Kyushu University , Fukuoka, 812-8582, Japan.
Org Lett. 2014 Apr 4;16(7):2018-21. doi: 10.1021/ol500593v. Epub 2014 Mar 24.
Lanthanum trifluoromethanesulfonate is an effective single-component catalyst for synthesizing a variety of amides directly from esters and amines under mild conditions. Highly selective amidation of esters and amines, as well as catalyst-controlled amidation of esters, demonstrated the effectiveness of the catalyst system.
三氟甲磺酸镧是一种有效的单组分催化剂,可在温和条件下直接由酯和胺合成各种酰胺。该催化剂体系对酯和胺的高选择性酰胺化以及酯的催化剂控制酰胺化反应具有很好的效果。