Organisch-Chemisches Institut, Universität Heidelberg, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany.
Chem Soc Rev. 2014 May 7;43(9):2941-55. doi: 10.1039/c3cs60441a. Epub 2014 Mar 27.
Although most mechanistic studies on gold-catalysed reactions focused on alkynes as substrates, some knowledge about gold-catalysed conversions of allenic substrates has been obtained. This contribution summarises these insights into the reaction mechanisms of gold-catalysed transformations of allenes which are based on computational studies, labelling studies, the detection of intermediates, chirality transfer and diastereoselective product formation.
尽管大多数关于金催化反应的机理研究都集中在炔烃作为底物上，但我们已经获得了一些关于金催化烯丙基底物转化的知识。本综述总结了基于计算研究、标记研究、中间体检测、手性转移和非对映选择性产物形成的金催化烯丙基转化反应机理的这些见解。
