State Key Laboratory of Silicon Materials, Cyrus Tang Center for Sensor Materials and Applications, Department of Materials Science and Engineering, Zhejiang University , Hangzhou, 310027, China.
J Am Chem Soc. 2014 Apr 16;136(15):5527-30. doi: 10.1021/ja411224j. Epub 2014 Apr 8.
Luminescent metal-organic framework films, CPM-5⊃Tb(3+) and MIL-100(In)⊃Tb(3+), have been constructed by postfunctionalization of two porous indium-organic frameworks with different structures, respectively. The MIL-100(In)⊃Tb(3+) film shows high oxygen sensitivity (KSV = 7.59) and short response/recovery time (6 s/53 s).
发光金属-有机骨架薄膜 CPM-5⊃Tb(3+)和 MIL-100(In)⊃Tb(3+)是通过对两种具有不同结构的多孔铟有机骨架进行后功能化构建而成的。MIL-100(In)⊃Tb(3+)薄膜具有高的氧灵敏度(KSV = 7.59)和短的响应/恢复时间(6 s/53 s)。