Lin Rui-Biao, Xiang Shengchang, Li Bin, Cui Yuanjing, Qian Guodong, Zhou Wei, Chen Banglin
Department of Chemistry, University of Texas at San Antonio, One UTSA Circle, San Antonio, TX 78249-0698, USA.
College of Chemistry and Chemical Engineering, Fujian Provincial Key Laboratory of Polymer Materials, Fujian Normal University, 32 Shangsan Road, Fuzhou 350007, China.
Coord Chem Rev. 2019 Apr;384. doi: 10.1016/j.ccr.2019.01.009.
Metal-organic frameworks (MOFs) are organic-inorganic hybrid solids constructed from the coordination interaction of metal ions/clusters with organic linkers, which currently represent one of the most rapidly expanding platforms for new functional materials. Based on well-established approaches, involving tuning the pore sizes, incorporation of functional sites and post-synthetic modification, the pore structures of MOFs can be readily controlled for multifunctional applications. In this brief review, we summarize and highlight our research progresses during our journey on developing functional MOFs for various applications including gas storage, gas separations, luminescent sensing, proton conduction, and molecular recognitions.
金属有机框架材料（MOFs）是由金属离子/簇与有机连接体通过配位相互作用构建而成的有机-无机杂化固体，目前它是新型功能材料中发展最为迅速的平台之一。基于成熟的方法，包括调节孔径、引入功能位点和进行后合成修饰，MOFs的孔结构能够很容易地得到控制以用于多功能应用。在这篇简短的综述中，我们总结并重点介绍了我们在开发用于各种应用（包括气体储存、气体分离、发光传感、质子传导和分子识别）的功能性MOFs过程中的研究进展。
