通过光氧化还原催化剂实现可见光介导的α-氨基烷基自由基与[60]富勒烯的加成反应。
Visible-light-mediated addition of α-aminoalkyl radicals to [60]fullerene by using photoredox catalysts.
作者信息
Miyake Yoshihiro, Ashida Yuya, Nakajima Kazunari, Nishibayashi Yoshiaki
机构信息
Institute of Engineering Innovation, School of Engineering, The University of Tokyo, Yayoi, Bunkyo-ku, Tokyo 113-8656 (Japan), Fax: (+81) 3-5841-1175; Present address: Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, 464-8603 (Japan).
出版信息
Chemistry. 2014 May 12;20(20):6120-5. doi: 10.1002/chem.201304731. Epub 2014 Apr 2.
The functionalization of fullerene has been extensively studied and various fullerene derivatives have been synthesized. We have succeeded in the functionalization of [60]fullerene by using α-aminoalkyl radicals generated by visible-light-mediated single-electron oxidation of α-silylamines as synthetic intermediates. In these reactions, the introduction of diarylamino groups, which are useful electron donors, has been easily achieved.
富勒烯的功能化已得到广泛研究，并且已合成了各种富勒烯衍生物。我们通过使用由α-硅烷基胺的可见光介导单电子氧化产生的α-氨基烷基自由基作为合成中间体，成功实现了[60]富勒烯的功能化。在这些反应中，易于实现有用的电子供体二芳基氨基的引入。
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