自然界中环丁烷的组装方式——来自量子化学的见解。
How cyclobutanes are assembled in nature--insights from quantum chemistry.
机构信息
Department of Chemistry, University of California-Davis, Davis, CA 95616, USA.
出版信息
Chem Soc Rev. 2014 Jul 21;43(14):5042-50. doi: 10.1039/c3cs60452g.
PMID:24710596
Abstract
Biosynthetic production of cyclobutanes leads to many complex natural products. Recently, theoretical work employing quantum chemical calculations has shed light on many of the details of cyclobutane-formation, in particular, for terpene natural products. Specific insights and general principles derived from these theoretical studies are described herein.
摘要
生物合成环丁烷的方法产生了许多复杂的天然产物。最近，利用量子化学计算的理论工作揭示了许多环丁烷形成的细节，特别是萜类天然产物。本文描述了这些理论研究中得出的具体见解和一般原则。
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