State Key Laboratory of Natural and Biomimetic Drugs, Peking University , Xue Yuan Road 38, Beijing 100191, China.
Org Lett. 2014 May 2;16(9):2302-5. doi: 10.1021/ol500793c. Epub 2014 Apr 15.
Copper-catalyzed oxoazidation and alkoxyazidation of indoles has been developed. The dearomatization reaction which leads to versatile 3-azido indolenine and oxindole derivatives in moderate to good yields could be used in a further transformation.
铜催化吲哚的羰氧化和烷氧基氧化已经被开发出来。该去芳构化反应以中等至良好的收率生成了多种 3-叠氮吲哚啉和氧化吲哚衍生物,可进一步转化。