Tripathi Pranav K, Gan Lihua, Liu Mingxian, Rao Nageswara N
J Nanosci Nanotechnol. 2014 Feb;14(2):1823-37. doi: 10.1166/jnn.2014.8763.
The transportation and diffusion of the guest objects or molecules in the porous carbon nanomaterials can be facilitated by reducing the pathway and resistance. The reduced pathway depends on the porous nature of carbon nanomaterials. Classification of porous carbon materials by the International Union of Pure and Applied Chemistry (IUPAC) has given a new opportunity to design the pores as per their applicability and to understand the mobility of ions, atoms, and molecules in the porous network of carbon materials and also advanced their countless applicability. However, synthesis of carbon nanomaterials with a desired porous network is still a great challenge. Although, remarkable developments have taken place in the recent years, control over the pores size and/or hierarchical porous architectures, especially in the synthesis of carbon nanospheres (CNSs) and ordered mesoporous carbon (OMCs) is still intriguing. The micro and mesoporous CNSs and OMCs have been prepared by a variety of procedures and over a wide range of compositions using various different surfactant templates and carbon precursors etc. The mechanisms of formation of micromesopore in the CNSs and OMCs are still evolving. On the other hand, the urge for adsorbents with very high adsorption capacities for removing contaminants from water is growing steadily. In this review, we address the state-of-the-art synthesis of micro and mesoporous CNSs and OMCs, giving examples of their applications for adsorptive removals of contaminants including our own research studies.
通过减少路径和阻力,可以促进客体物体或分子在多孔碳纳米材料中的传输和扩散。路径的缩短取决于碳纳米材料的多孔性质。国际纯粹与应用化学联合会(IUPAC)对多孔碳材料的分类为根据其适用性设计孔隙以及理解离子、原子和分子在碳材料多孔网络中的迁移率提供了新的契机,同时也拓展了它们无数的应用。然而,合成具有所需多孔网络的碳纳米材料仍然是一个巨大的挑战。尽管近年来取得了显著进展,但对孔径大小和/或分级多孔结构的控制,尤其是在碳纳米球(CNSs)和有序介孔碳(OMCs)的合成中,仍然颇具吸引力。已经通过多种方法并使用各种不同的表面活性剂模板和碳前驱体等,在广泛的组成范围内制备了微孔和介孔CNSs以及OMCs。CNSs和OMCs中微孔介孔的形成机制仍在不断发展。另一方面,对具有极高吸附能力以去除水中污染物的吸附剂的需求正在稳步增长。在本综述中,我们阐述了微孔和介孔CNSs以及OMCs的最新合成方法,并举例说明了它们在吸附去除污染物方面的应用,包括我们自己的研究。