Faculty of Chemistry, Biological and Chemical Research Centre, University of Warsaw, Żwirki i Wigury 101, Warsaw, 02-089 (Poland).
Angew Chem Int Ed Engl. 2014 Jun 16;53(25):6464-7. doi: 10.1002/anie.201402049. Epub 2014 Apr 24.
Diffusion-ordered multidimensional NMR spectroscopy is a valuable technique for the analysis of complex chemical mixtures. However, this method is very time-consuming because of the costly sampling of a multidimensional signal. Various sparse sampling techniques have been proposed to accelerate such measurements, but they have always been limited to frequency dimensions of NMR spectra. It is now revealed how sparse sampling can be extended to diffusion dimensions.
扩散排序多维核磁共振波谱是分析复杂化学混合物的一种很有价值的技术。然而,由于多维信号的采样代价昂贵,这种方法非常耗时。已经提出了各种稀疏采样技术来加速这种测量,但它们始终局限于核磁共振谱的频率维度。现在揭示了如何将稀疏采样扩展到扩散维度。