• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

双[(2-甲基苄基)双-(吡啶-2-基甲基-κN)胺-κN]锰(II) 双(高氯酸盐)

Bis[(2-methyl-benz-yl)bis-(pyridin-2-ylmethyl-κN)amine-κN]manganese(II) bis-(perchlorate).

作者信息

Butcher Ray J, Gultneh Yilma, Yisgedu T B

机构信息

Department of Chemistry, Howard University, 525 College Street NW, Washington, DC 20059, USA.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2014 Feb 15;70(Pt 3):m100-1. doi: 10.1107/S1600536814003055. eCollection 2014 Mar 1.

DOI:10.1107/S1600536814003055
PMID:24764935
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3998448/
Abstract

In the title complex, Mn(C20H21N3)22, two tridentate (2-methyl-benz-yl)bis-(pyridin-2-ylmeth-yl)amine (L) ligands form the Mn(II) complex MnL 22. The Mn(II) ion lies on a twofold axis and the complex cation is significantly distorted from regular octa-hedral geometry. The packing is stabilized by weak C-H⋯O inter-actions between the cations and anions, which link them into a zigzag ribbon along [101]. The perchlorate anion is disordered and was constrained to be tetra-hedral with two orientations having occupancies of 0.768 (4) and 0.232 (4). The 2-methylbenzyl moiety is also disordered over two sets of sites, with occupancies of 0.508 (15) and 0.492 (15).

摘要

在标题配合物Mn(C₂₀H₂₁N₃)₂₂中，两个三齿的(2-甲基苄基)双(吡啶-2-基甲基)胺(L)配体形成了Mn(II)配合物MnL₂₂。Mn(II)离子位于二重轴上，配合物阳离子明显偏离正八面体几何构型。阳离子和阴离子之间的弱C-H⋯O相互作用使堆积得以稳定，这些相互作用将它们沿[101]连接成一条锯齿状带。高氯酸根阴离子无序，被限制为四面体，有两种取向，占有率分别为0.768 (4)和0.232 (4)。2-甲基苄基部分也在两组位置上无序，占有率分别为0.508 (15)和0.492 (15)。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ead/3998448/91c311d1aaa0/e-70-0m100-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ead/3998448/bbac3c97e270/e-70-0m100-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ead/3998448/91c311d1aaa0/e-70-0m100-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ead/3998448/bbac3c97e270/e-70-0m100-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ead/3998448/91c311d1aaa0/e-70-0m100-fig2.jpg

相似文献

1
Bis[(2-methyl-benz-yl)bis-(pyridin-2-ylmethyl-κN)amine-κN]manganese(II) bis-(perchlorate).双[(2-甲基苄基)双-(吡啶-2-基甲基-κN)胺-κN]锰(II) 双(高氯酸盐)
Acta Crystallogr Sect E Struct Rep Online. 2014 Feb 15;70(Pt 3):m100-1. doi: 10.1107/S1600536814003055. eCollection 2014 Mar 1.
2
trans-Tetra-aqua-bis-[bis-(pyridin-3-yl)methanone-κN]manganese(II) bis-(perchlorate).反式-四水合-双-[双-(吡啶-3-基)甲酮-κN]锰(II) 双(高氯酸盐)
Acta Crystallogr Sect E Struct Rep Online. 2012 Jan;68(Pt 1):m25. doi: 10.1107/S1600536811052184. Epub 2011 Dec 10.
3
Bis[N-(3-amino-prop-yl)propane-1,3-di-amine-κN,N',N'']cadmium nitrate perchlorate.双[N-(3-氨基丙基)丙烷-1,3-二胺-κN,N',N'']镉高氯酸硝酸盐
Acta Crystallogr Sect E Struct Rep Online. 2012 Mar 1;68(Pt 3):m273-4. doi: 10.1107/S1600536812004400. Epub 2012 Feb 10.
4
(Dimethyl-formamide-κO)(2-hy-droxy-benzoato-κO,O)[tris-(1-methyl-1H-benzimidazol-2-ylmethyl-κN)amine-κN]manganese(II) perchlorate dimethyl-formamide monosolvate.高氯酸（二甲基甲酰胺-κO）（2-羟基苯甲酸根-κO，O）[三（1-甲基-1H-苯并咪唑-2-基甲基-κN）胺-κN]锰（II）二甲基甲酰胺单溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 11;66(Pt 10):m1252. doi: 10.1107/S160053681003610X.
5
Crystal structure of tetra-kis-(μ-()-2,4-di-bromo-6-{[2-(pyridin-2-yl)eth-yl]imino-meth-yl}phen-olato)trizinc bis-(perchlorate) aceto-nitrile disolvate.四 - 双 -（μ -（）-2,4 - 二溴 - 6 - {[2 -（吡啶 - 2 - 基）乙基]亚氨基甲基}苯酚根）三锌双（高氯酸盐）乙腈二溶剂合物的晶体结构
Acta Crystallogr E Crystallogr Commun. 2018 Aug 31;74(Pt 9):1380-1383. doi: 10.1107/S2056989018012100. eCollection 2018 Sep 1.
6
Crystal structure of an eight-coordinate terbium(III) ion chelated by N,N'-bis-(2-hy-droxy-benz-yl)-N,N'-bis-(pyridin-2-ylmeth-yl)ethyl-enedi-amine (bbpen(2-)) and nitrate.由N,N'-双-(2-羟基苄基)-N,N'-双-(吡啶-2-基甲基)乙二胺（bbpen(2-)）和硝酸根螯合的八配位铽(III)离子的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Jan 1;71(Pt 1):65-8. doi: 10.1107/S2056989014026826.
7
catena-Poly[[[bis-(methanol-κO)bis-(seleno-cyanato-κN)manganese(II)]-μ-1,2-bis-(pyridin-4-yl)ethane-κ(2) N:N'] 1,2-bis-(pyridin-4-yl)ethane monosolvate].链状聚[[[双（甲醇-κO）双（硒氰酸根-κN）锰（II）]-μ-1,2-双（吡啶-4-基）乙烷-κ(2) N:N'] 1,2-双（吡啶-4-基）乙烷单溶剂合物]
Acta Crystallogr Sect E Struct Rep Online. 2013 Mar 20;69(Pt 4):m223. doi: 10.1107/S1600536813007150. Print 2013 Apr 1.
8
Crystal structure of aqua-(perchlorato)bis-[μ-()-2-({[2-(pyridin-2-yl)eth-yl]imino}-meth-yl)phenolato-κ,',:]dicopper(II) perchlorate.高氯酸水合-（高氯酸根）双-[μ-（）-2-（{[2-（吡啶-2-基）乙基]亚氨基}-甲基）苯酚根-κ，'，：]二铜（II）的晶体结构
Acta Crystallogr E Crystallogr Commun. 2017 Oct 20;73(Pt 11):1708-1711. doi: 10.1107/S2056989017014694. eCollection 2017 Nov 1.
9
Bis[N,N-bis-(1-allyl-1H-benzimidazol-2-ylmethyl-κN)benzyl-amine-κN]cadmium dipicrate.双[ N，N - 双 -（1 - 烯丙基 - 1H - 苯并咪唑 - 2 - 基亚甲基 - κN）苄基胺 - κN]镉二苦味酸盐
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m800-1. doi: 10.1107/S1600536811019180. Epub 2011 May 25.
10
catena-Poly[[[di-aqua-bis-[1,2-bis-(pyridin-4-yl)diazene]copper(II)]-μ-1,2-bis-(pyridin-4-yl)diazene] bis-(perchlorate)].链状聚[[[二水合双-[1,2-双-(吡啶-4-基)二氮烯]铜(II)]-μ-1,2-双-(吡啶-4-基)二氮烯]双-(高氯酸盐)]
Acta Crystallogr Sect E Struct Rep Online. 2013 May 15;69(Pt 6):m317-8. doi: 10.1107/S1600536813012269. Print 2013 Jun 1.

引用本文的文献

1
The repurposing of Tebipenem pivoxil as alternative therapy for severe gastrointestinal infections caused by extensively drug-resistant spp.替比培南匹伏酯重新用作广泛耐药菌引起的严重胃肠道感染的替代疗法
Elife. 2022 Mar 15;11:e69798. doi: 10.7554/eLife.69798.

本文引用的文献

1
Nuclease and anti-proliferative activities of copper(II) complexes of N3O tripodal ligands involving a sterically hindered phenolate.涉及位阻酚酸盐的 N3O 三足配体的铜（II）配合物的核酸酶和抗增殖活性。
Dalton Trans. 2013 Jun 21;42(23):8468-83. doi: 10.1039/c3dt32659d. Epub 2013 Apr 26.
2
Palladium(II) saccharinate complexes with bis(2-pyridylmethyl)amine induce cell death by apoptosis in human breast cancer cells in vitro.钯(II) saccharinate 配合物与双(2-吡啶甲基)胺在体外诱导人乳腺癌细胞凋亡死亡。
Bioorg Med Chem. 2013 Jun 1;21(11):3016-21. doi: 10.1016/j.bmc.2013.03.073. Epub 2013 Apr 6.
3
Trifunctional metal ion-catalyzed solvolysis: Cu(II)-promoted methanolysis of N,N-bis(2-picolyl) benzamides involves unusual Lewis acid activation of substrate, delivery of coordinated nucleophile, powerful assistance of the leaving group departure.
三功能金属离子催化的溶剂解：Cu(II)促进的 N,N-双(2-吡啶基)苯甲酰胺的甲醇解涉及到底物的不寻常的路易斯酸活化、配位亲核试剂的传递、离去基团离去的强大辅助作用。
Inorg Chem. 2012 Oct 1;51(19):10325-33. doi: 10.1021/ic301454y. Epub 2012 Sep 12.
4
The formation of a luminescent Mn(III,IV) intermediate of bis(2-pyridylmethyl)amine and acetone assistant its intramolecular C-H oxidation.双（2-吡啶甲基）胺和丙酮辅助形成的发光 Mn(III,IV) 中间体能促进其分子内的 C-H 氧化。
Spectrochim Acta A Mol Biomol Spectrosc. 2011 Oct 15;81(1):604-8. doi: 10.1016/j.saa.2011.06.062. Epub 2011 Jul 6.
5
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
6
Oxidant types in copper-dioxygen chemistry: the ligand coordination defines the Cu(n)-O2 structure and subsequent reactivity.铜-氧气化学中的氧化剂类型：配体配位决定了Cu(n)-O₂结构及后续反应活性。
J Biol Inorg Chem. 2004 Sep;9(6):669-83. doi: 10.1007/s00775-004-0578-4. Epub 2004 Aug 10.
7
Bright fluorescent chemosensor platforms for imaging endogenous pools of neuronal zinc.用于成像神经元锌内源性池的明亮荧光化学传感器平台。
Chem Biol. 2004 Feb;11(2):203-10. doi: 10.1016/j.chembiol.2004.01.017.
8
Catalytic asymmetric synthesis.
Acc Chem Res. 2000 Jun;33(6):324. doi: 10.1021/ar000046x.