El-Hiti Gamal A, Smith Keith, Balakit Asim A, Hegazy Amany S, Kariuki Benson M
Department of Optometry, College of Applied Medical Sciences, King Saud University, PO Box 10219, Riyadh 11433, Saudi Arabia.
School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, Wales.
Acta Crystallogr Sect E Struct Rep Online. 2014 Feb 26;70(Pt 3):o351-2. doi: 10.1107/S1600536814003729. eCollection 2014 Mar 1.
In the title compound, C11H16N2O, the dihedral angle between the mean plane of the 4-methypyridine group and the plane of the amide link is 16.7 (1)°, and there is a short intra-molecular C-H⋯O contact. Hydrogen bonding (N-H⋯O) between amide groups forms chains parallel to the b axis. Pairs of methyl-pyridine groups from mol-ecules in adjacent chains are parallel but there is minimal π-π inter-action.
在标题化合物C₁₁H₁₆N₂O中,4-甲基吡啶基团的平均平面与酰胺键平面之间的二面角为16.7 (1)°,并且存在短的分子内C-H⋯O接触。酰胺基团之间的氢键(N-H⋯O)形成平行于b轴的链。相邻链中分子的甲基吡啶基团对是平行的,但π-π相互作用最小。