State Key Laboratory of Applied Organic Chemistry, Lanzhou University , Lanzhou 730000, China.
Org Lett. 2014 Jun 20;16(12):3173-5. doi: 10.1021/ol501308p. Epub 2014 May 28.
The first total synthesis of indole alkaloid (±)-subincanadine E has been accomplished. Ni(COD)2-mediated intramolecular Michael addition and zinc-mediated fragmentation reaction served as two key transformations.
吲哚生物碱(±)-subincanadine E 的首次全合成已经完成。Ni(COD)2 介导的分子内迈克尔加成和锌介导的断裂反应是两个关键转化。