通过(n)Bu4NI催化乙苯的多个sp(3)C-H键氧化并与二烷基甲酰胺顺序偶联合成α-酮酰胺。
The syntheses of α-ketoamides via(n)Bu4NI-catalyzed multiple sp(3)C-H bond oxidation of ethylarenes and sequential coupling with dialkylformamides.
作者信息
Du Bingnan, Jin Bo, Sun Peipei
机构信息
Jiangsu Key Laboratory of Biofunctional Materials, College of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210097, China.
出版信息
Org Biomol Chem. 2014 Jul 14;12(26):4586-9. doi: 10.1039/c4ob00520a.
PMID:24871997
Abstract
The (n)Bu4NI-catalyzed sequential C-O and C-N bond formation via multiple sp(3)C-H bond activation of ethylarenes, using N,N-dialkylformamide as the amino source, provided α-ketoamides with moderate yields.
摘要
以N，N-二烷基甲酰胺为氨基源，通过乙苯的多个sp(3)C-H键活化，在(n)Bu4NI催化下依次形成C-O键和C-N键，以中等产率得到α-酮酰胺。
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