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[兰州大气沉降中重金属的污染评价与健康风险评估]

[Pollution evaluation and health risk assessment of heavy metals from atmospheric deposition in Lanzhou].

作者信息

Li Ping, Xue Su-Yin, Wang Sheng-Li, Nan Zhong-Ren

出版信息

Huan Jing Ke Xue. 2014 Mar;35(3):1021-8.

Abstract

In order to evaluate the contamination and health risk of heavy metals from atmospheric deposition in Lanzhou, samples of atmospheric deposition were collected from 11 sampling sites respectively and their concentrations of heavy metals were determined. The results showed that the average contents of Cu, Pb, Cd, Cr, Ni, Zn and Mn were 82.22, 130.31, 4.34, 88.73, 40.64, 369.23 and 501.49 mg x kg(-1), respectively. There was great difference among different functional areas for all elements except Mn. According to the results, the enrichment factor score of Mn was close to 1, while the enrichment of Zn, Ni, Cu and Cr was more serious, and Pb and Cd were extremely enriched. The assessment results of geoaccumulation index of potential ecological risk indicated that the pollution of Cd in the atmospheric deposition of Lanzhou should be classified as extreme degree, and that of Cu, Ni, Zn, Pb as between slight and extreme degrees, and Cr as practically uncontaminated. Contaminations of atmospheric dust by heavy metals in October to the next March were more serious than those from April to August. Health risk assessment indicated that the heavy metals in atmospheric deposition were mainly ingested by human bodies through hand-mouth ingestion. The non-cancer risk was higher for children than for adults. The order of non-cancer hazard indexes of heavy metals was Pb > Cr > Cd > Cu > Ni > Zn. The non-cancer hazard indexes and carcinogen risks of heavy metals were both lower than their threshold values, suggesting that they will not harm the health.

摘要

为评估兰州市大气沉降中重金属的污染状况及健康风险,分别在11个采样点采集大气沉降样品并测定其重金属含量。结果表明,Cu、Pb、Cd、Cr、Ni、Zn和Mn的平均含量分别为82.22、130.31、4.34、88.73、40.64、369.23和501.49 mg·kg⁻¹。除Mn外,各元素在不同功能区之间存在较大差异。结果显示,Mn的富集因子得分接近1,而Zn、Ni、Cu和Cr的富集较为严重,Pb和Cd极度富集。潜在生态风险地累积指数评价结果表明,兰州市大气沉降中Cd的污染程度为极重度,Cu、Ni、Zn、Pb为轻度至极重度,Cr几乎未受污染。10月至次年3月大气降尘中重金属污染比4月至8月更为严重。健康风险评估表明,大气沉降中的重金属主要通过手口摄入途径进入人体。儿童的非致癌风险高于成人。重金属非致癌危害指数顺序为Pb>Cr>Cd>Cu>Ni>Zn。重金属的非致癌危害指数和致癌风险均低于其阈值,表明不会对健康造成危害。

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