Zhang Sheng, Liu Xiangyu, Yang Qi, Su Zhiyong, Gao Wenjuan, Wei Qing, Xie Gang, Chen Sanping, Gao Shengli
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry, Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, Shaanxi 710069 (P. R China).
Chemistry. 2014 Jun 23;20(26):7906-10. doi: 10.1002/chem.201402783. Epub 2014 May 30.
Reaction of Co(II) with the nitrogen-rich ligand N,N-bis(1H-tetrazole-5-yl)-amine (H2bta) leads to a mixed-valence, 3D, porous, metal-organic framework (MOF)-based, energetic material with the nitrogen content of 51.78%, [Co9(bta)10(Hbta)2(H2O)10]n⋅(22 H2O)n (1). Compound 1 was thermohydrated to produce a new, stable, energetic material with the nitrogen content of 59.85% and heat of denotation of 4.537 kcal cm(-3), [Co9(bta)10(Hbta)2(H2O)10]n (2). Sensitivity tests show that 2 is more sensitivity to external stimuli than 1, reflecting guest-dependent energy and sensitivity of 3D, MOF-based, energetic materials. Less-sensitive 1 can be regarded as a more safe form for storage and transformation to sensitive 2.
钴（II）与富氮配体N，N-双（1H-四唑-5-基）-胺（H2bta）反应生成一种基于三维多孔金属有机骨架（MOF）的混合价态含能材料，氮含量为51.78%，即[Co9(bta)10(Hbta)2(H2O)10]n⋅(22 H2O)n（1）。化合物1经过热脱水处理后得到一种新的、稳定的含能材料，氮含量为59.85%，爆热为4.537 kcal cm(-3)，即[Co9(bta)10(Hbta)2(H2O)10]n（2）。敏感性测试表明，化合物2对外部刺激的敏感性高于化合物1，这反映了基于三维MOF的含能材料的客体依赖性能量和敏感性。敏感性较低的化合物1可被视为一种更安全的储存形式，并可转化为敏感性较高的化合物2。
