Chu Xue-Qiang, Zi You, Meng Hua, Xu Xiao-Ping, Ji Shun-Jun
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, 215123, People's Republic of China.
Chem Commun (Camb). 2014 Jul 21;50(57):7642-5. doi: 10.1039/c4cc02114b.
A novel radical phosphinylation of α,α-diaryl allylic alcohols with arylphosphine oxides was described for the direct preparation of α-aryl-β-phosphinylated carbonyl ketones in medium to good yields via 1,2-aryl migration. In this reaction, formation of new C(Ar)-C(sp(3)) and C(sp(3))-P bonds was observed.
描述了一种新型的α,α-二芳基烯丙醇与芳基氧化膦的自由基膦酰化反应，通过1,2-芳基迁移直接制备α-芳基-β-膦酰化羰基酮，产率中等至良好。在该反应中，观察到形成了新的C(Ar)-C(sp(3))和C(sp(3))-P键。
