Alemayehu Abraham B, Vazquez-Lima Hugo, Beavers Christine M, Gagnon Kevin J, Bendix Jesper, Ghosh Abhik
Department of Chemistry and Center for Theoretical and Computational Chemistry, UiT - The Arctic University of Norway, 9037 Tromsø, Norway.
Chem Commun (Camb). 2014 Oct 4;50(76):11093-6. doi: 10.1039/c4cc02548b.
Platinum has been inserted into corroles for the first time and three oxidized Pt(IV)(corrole˙(2-))ArAr' complexes have been structurally characterized. The Soret maxima of these complexes exhibit an unusually strong dependence on the meso-aryl substituents on the corrole, indicating aryl → corrole˙(2-) charge transfer character in these transitions.
铂首次被引入到卟吩中，并且对三种氧化态的Pt(IV)(corrole˙(2-))ArAr'配合物进行了结构表征。这些配合物的Soret吸收峰极大值对卟吩上的中位芳基取代基表现出异常强烈的依赖性，表明在这些跃迁中存在芳基→corrole˙(2-)的电荷转移特性。
