Department of Chemistry, University of Florida, Gainesville, FL 32611-7200, USA.
Molecules. 2014 Jun 10;19(6):7689-713. doi: 10.3390/molecules19067689.
Methods to convert amines to formamides are of interest due to the many uses of formamides as synthetic intermediates. These methods include stoichiometric reactions of formylating reagents and catalytic reactions with CO as the carbonyl source. This review discusses the reported stoichiometric and catalytic approaches for preparation of formamides.
由于甲酰胺作为合成中间体的许多用途,将胺转化为甲酰胺的方法引起了人们的兴趣。这些方法包括使用甲酰化试剂的化学计量反应和使用 CO 作为羰基源的催化反应。本文综述了报道的制备甲酰胺的化学计量和催化方法。