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新型纳米复合水凝胶由层状双氢氧化物组成,具有超高拉伸性和低无机含量下的分级多孔结构。

Novel nanocomposite hydrogels consisting of layered double hydroxide with ultrahigh tensibility and hierarchical porous structure at low inorganic content.

机构信息

Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. China.

出版信息

Adv Mater. 2014 Sep 10;26(34):5950-6. doi: 10.1002/adma.201400179. Epub 2014 Jun 13.

DOI:10.1002/adma.201400179
PMID:24923256
Abstract

A novel type of polymer nanocomposite (NC) hydrogel with extraordinary mechanical properties at low inorganic content is prepared and investigated. The NC hydrogels consist of isethionate-loaded layered double hydroxide/polyacrylamide (LDH-Ise/PAM) - with LDH-Ise being used because of its swelling properties - and no conventional organic crosslinker. The NC hydrogels exhibit an unusual hierarchical porous structure at the micro- and nanometer scales, and their elongation at break can exceed 4000%.

摘要

制备并研究了一种新型聚合物纳米复合材料(NC)水凝胶,其在低无机含量下具有非凡的机械性能。NC 水凝胶由载有伊士酸盐的层状双氢氧化物/聚丙烯酰胺(LDH-Ise/PAM)组成 - 之所以使用 LDH-Ise 是因为其具有溶胀性能 - 且不使用常规的有机交联剂。NC 水凝胶在微观和纳米尺度上呈现出异常的分级多孔结构,其断裂伸长率可超过 4000%。

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