（乙腈-κN）碘化双（三苯基膦-κP）铜（I）
(Aceto-nitrile-κN)iodidobis(tri-phenylphosphane-κP)copper(I).
作者信息
Wattanakanjana Yupa, Nimthong Arunpatcha, Mokakul Jedsada, Sukpornsawan Phattarin
机构信息
Department of Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112, Thailand.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2014 May 17;70(Pt 6):m219. doi: 10.1107/S1600536814010940. eCollection 2014 Jun 1.
In the mononuclear title complex, [CuI(CH3CN)(C18H15P)2], the Cu(I) ion is in a distorted tetra-hedral geometry, coordinated by two P atoms of two tri-phenyl-phosphane ligands, one N atom of an aceto-nitrile ligand and one iodide anion. The aceto-nitrile ligand is disordered over two sets of sites in a 0.629 (15): 0.371 (15) ratio. In the crystal, weak C-H⋯I hydrogen bonds link the mol-ecules, forming a chain along [100].
在单核标题配合物[CuI(CH₃CN)(C₁₈H₁₅P)₂]中，Cu(I)离子处于扭曲的四面体几何构型，由两个三苯基膦配体的两个P原子、一个乙腈配体的一个N原子和一个碘阴离子配位。乙腈配体在两组位置上无序排列，比例为0.629 (15): 0.371 (15)。在晶体中，弱的C—H⋯I氢键连接分子，沿[100]方向形成一条链。
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