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基于席夫碱作为螯合离子载体的膜传感器——综述

Membrane sensors based on Schiff bases as chelating ionophores--a review.

作者信息

Al Zoubi Wail, Al Mohanna NaDeem

机构信息

Department of Chemistry, Faculty of Science, University of Damascus, Syria.

Department of Chemistry, Faculty of Science, University of Damascus, Syria.

出版信息

Spectrochim Acta A Mol Biomol Spectrosc. 2014 Nov 11;132:854-70. doi: 10.1016/j.saa.2014.04.176. Epub 2014 Jun 3.

Abstract

The development of chemical sensors has received widespread attention during the past two decades because of their extensive use in environmental monitoring and clinical analysis via rapid, accurate, reproducible, and low-cost methods. Chemically modified CPEs have frequently been employed as potentiometric sensors in trace analysis for metal ions, organic pollutants and biological substances. Most of these electrodes are operated via the ion-exchange process of the active component incorporated into the carbon paste matrix. This review article concentrates on such achievements in the context of the general development across the field. An overview of potentiometric sensors that are capable of detecting metal ions in environmental samples is presented and discussed. A survey on important advances in potentiometric sensors with regard to high selectivity, lower detection limit, and fast response time is presented in this review article.

摘要

在过去二十年中,化学传感器的发展受到了广泛关注,因为它们通过快速、准确、可重复且低成本的方法在环境监测和临床分析中得到了广泛应用。化学修饰的碳糊电极(CPEs)经常被用作电位传感器,用于金属离子、有机污染物和生物物质的痕量分析。这些电极大多通过掺入碳糊基质中的活性成分的离子交换过程来工作。本文综述集中于该领域总体发展背景下的此类成果。文中给出并讨论了能够检测环境样品中金属离子的电位传感器的概述。本文综述了电位传感器在高选择性、更低检测限和快速响应时间方面的重要进展。

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