Rubio-Martinez Marta, Batten Michael P, Polyzos Anastasios, Carey Keri-Constanti, Mardel James I, Lim Kok-Seng, Hill Matthew R
CSIRO Process Science and Engineering, Private Bag 33, Clayton South MDC VIC 3169, Australia.
CSIRO Earth Sciences and Resource Engineering Private Bag 33, Clayton South MDC VIC 3169, Australia.
Sci Rep. 2014 Jun 25;4:5443. doi: 10.1038/srep05443.
Further deployment of Metal-Organic Frameworks in applied settings requires their ready preparation at scale. Expansion of typical batch processes can lead to unsuccessful or low quality synthesis for some systems. Here we report how continuous flow chemistry can be adapted as a versatile route to a range of MOFs, by emulating conditions of lab-scale batch synthesis. This delivers ready synthesis of three different MOFs, with surface areas that closely match theoretical maxima, with production rates of 60 g/h at extremely high space-time yields.
要在应用场景中进一步部署金属有机框架，需要能够大规模地随时制备它们。对于某些体系而言，扩大典型的分批处理过程可能会导致合成失败或质量低下。在此，我们报告了如何通过模拟实验室规模分批合成的条件，将连续流化学作为一种通用途径来制备一系列金属有机框架。这实现了三种不同金属有机框架的快速合成，其表面积与理论最大值紧密匹配，在极高的时空产率下生产率达到60 g/h。
