用于储氢的高多孔且坚固的基于钪的金属有机骨架。
Highly porous and robust scandium-based metal-organic frameworks for hydrogen storage.
机构信息
School of Chemistry, University of Nottingham, University Park, Nottingham NG7 2RD, UK.
出版信息
Chem Commun (Camb). 2011 Aug 7;47(29):8304-6. doi: 10.1039/c1cc11168j. Epub 2011 Jun 20.
PMID:21691622
Abstract
The metal-organic frameworks NOTT-400 and NOTT-401, based on a binuclear [Sc(2)(μ(2)-OH)(O(2)CR)(4)] building block, have been synthesised and characterised; the desolvated framework NOTT-401a shows a BET surface area of 1514 m(2) g(-1) with a total H(2) uptake of 4.44 wt% at 77 K and 20 bar.
摘要
基于双核[Sc(2)(μ(2)-OH)(O(2)CR)(4)]构筑块的金属-有机骨架 NOTT-400 和 NOTT-401 已被合成并进行了表征；脱去溶剂的 NOTT-401a 骨架在 77 K 和 20 巴下具有 1514 m(2) g(-1)的 BET 表面积和 4.44 wt%的总氢气吸收量。
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