Yang Sudong, Chen Lin, Mu Lei, Ma Peng-Cheng
Laboratory of Environmental Science and Technology, The Xinjiang Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Urumqi 830011, China; Key Laboratory of Functional Materials and Devices for Special Environments, Chinese Academy of Sciences, Urumqi 830011, China.
Laboratory of Environmental Science and Technology, The Xinjiang Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Urumqi 830011, China.
J Colloid Interface Sci. 2014 Sep 15;430:337-44. doi: 10.1016/j.jcis.2014.05.062. Epub 2014 Jun 9.
This paper reported the preparation of magnetic graphene foam loaded with magnetite (Fe3O4) nanoparticles and its application for the adsorption of oil and organic solvents. The foam with porous and hierarchical structures was derived from graphene oxide film reduced by gaseous reduction in a hydrothermal system. Drastically different morphologies of Fe3O4 nanoparticles with nanosheet arrays or cubic structures were observed on graphene foam by controlling the reduction degree of graphene oxide under mild conditions. Benefiting from the integration of porous structures and magnetic properties, the graphene foam manifests outstanding oil adsorption capacity, high restoration for absorbates as well as excellent recyclability and stability under cyclic operations. The simple and effective strategy for the preparation of graphene foams developed in this study may offer a new alternative for scale-up production of graphene materials used for the cleanup of oil spills.
本文报道了负载磁铁矿(Fe3O4)纳米颗粒的磁性石墨烯泡沫的制备及其在油和有机溶剂吸附中的应用。具有多孔和分级结构的泡沫由水热体系中通过气体还原还原氧化石墨烯薄膜得到。通过在温和条件下控制氧化石墨烯的还原程度,在石墨烯泡沫上观察到具有纳米片阵列或立方结构的Fe3O4纳米颗粒的截然不同的形态。得益于多孔结构和磁性的结合,石墨烯泡沫表现出出色的吸油能力、对吸附物的高恢复性以及在循环操作下优异的可回收性和稳定性。本研究中开发的制备石墨烯泡沫的简单有效策略可能为大规模生产用于清理溢油的石墨烯材料提供新的选择。