Department of Inorganic Chemistry, Dresden University of Technology , Bergstraße 66, Dresden 01069, Germany.
ACS Nano. 2014 Jul 22;8(7):7138-46. doi: 10.1021/nn502065u. Epub 2014 Jul 2.
Conductive polymers showing stretchable and transparent properties have received extensive attention due to their enormous potential in flexible electronic devices. Here, we demonstrate a facile and smart strategy for the preparation of structurally stretchable, electrically conductive, and optically semitransparent polyaniline-containing hybrid hydrogel networks as electrode, which show high-performances in supercapacitor application. Remarkably, the stability can extend up to 35,000 cycles at a high current density of 8 A/g, because of the combined structural advantages in terms of flexible polymer chains, highly interconnected pores, and excellent contact between the host and guest functional polymer phase.
具有拉伸和透明性能的导电聚合物由于其在柔性电子设备中的巨大潜力而受到广泛关注。在这里,我们展示了一种简便而智能的策略,用于制备结构可拉伸、导电和光学半透明的含聚苯胺混合水凝胶网络作为电极,其在超级电容器应用中表现出优异的性能。值得注意的是,由于柔性聚合物链、高度互连的孔以及主体和客体功能聚合物相之间的优异接触的综合结构优势,在 8 A/g 的高电流密度下,稳定性可延长至 35000 个循环。