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基于导电聚合物的凝胶材料:合成、形态、热性能及在超级电容器中的应用

Conducting Polymer-Based Gel Materials: Synthesis, Morphology, Thermal Properties, and Applications in Supercapacitors.

作者信息

Rahman Khan Mohammad Mizanur, Chakraborty Nilave

机构信息

Department of Mechanical Engineering, Gachon University-1342, Seongnam-daero, Sujeong-gu, Seongnam-si 13120, Gyeonggi-do, Republic of Korea.

Department of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, UT 84112-0850, USA.

出版信息

Gels. 2024 Aug 26;10(9):553. doi: 10.3390/gels10090553.

Abstract

Despite the numerous ongoing research studies in the area of conducting polymer-based electrode materials for supercapacitors, the implementation has been inadequate for commercialization. Further understanding is required for the design and synthesis of suitable materials like conducting polymer-based gels as electrode materials for supercapacitor applications. Among the polymers, conductive polymer gels (CPGs) have generated great curiosity for their use as supercapacitors, owing to their attractive qualities like integrated 3D porous nanostructures, softness features, very good conductivity, greater pseudo capacitance, and environmental friendliness. In this review, we describe the current progress on the synthesis of CPGs for supercapacitor applications along with their morphological behaviors and thermal properties. We clearly explain the synthesis approaches and related phenomena, including electrochemical approaches for supercapacitors, especially their potential applications as supercapacitors based on these materials. Focus is also given to the recent advances of CPG-based electrodes for supercapacitors, and the electrochemical performances of CP-based promising composites with CNT, graphene oxides, and metal oxides is discussed. This review may provide an extensive reference for forthcoming insights into CPG-based supercapacitors for large-scale applications.

摘要

尽管在用于超级电容器的导电聚合物基电极材料领域有众多正在进行的研究,但该技术在商业化方面的应用仍不充分。对于设计和合成诸如用于超级电容器应用的导电聚合物基凝胶等合适材料,还需要进一步了解。在聚合物中,导电聚合物凝胶(CPG)因其具有集成的三维多孔纳米结构、柔软特性、良好的导电性、较大的赝电容和环境友好性等吸引人的品质,作为超级电容器的应用引发了极大的关注。在这篇综述中,我们描述了用于超级电容器应用的CPG合成的当前进展及其形态行为和热性能。我们清楚地解释了合成方法及相关现象,包括超级电容器的电化学方法,特别是它们基于这些材料作为超级电容器的潜在应用。还重点介绍了用于超级电容器的基于CPG的电极的最新进展,并讨论了基于CP的与碳纳米管、氧化石墨烯和金属氧化物的有前景的复合材料的电化学性能。这篇综述可为即将到来的大规模应用的基于CPG的超级电容器的深入研究提供广泛的参考。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f138/11431190/3b64ea573179/gels-10-00553-g008.jpg

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