The benzoyl peroxide-promoted functionalization of simple alkanes with 2-aryl phenyl isonitrile.
作者信息
Sha Wanxing, Yu Jin-Tao, Jiang Yan, Yang Haitao, Cheng Jiang
机构信息
School of Petrochemical Engineering, Jiangsu Key Laboratory of Advanced Catalytic Materials & Technology, and Jiangsu Province Key Laboratory of Fine Petrochemical Engineering, Changzhou University, 1 Gehu Road, Changzhou, 213164, P. R. China.
出版信息
Chem Commun (Camb). 2014 Aug 21;50(65):9179-81. doi: 10.1039/c4cc03304c.
PMID:24993445
Abstract
The benzoyl peroxide (BPO)-promoted phenanthridinylation of simple alkanes with isonitrile is developed via C(sp(3))-H and C(sp(2))-H bond cleavage. This procedure is featured by dual C-C bond formation proceeding with the addition of an alkyl radical to isonitrile followed by radical aromatic cyclization.
摘要
Zotero 插件