Crochet Pascale, Cadierno Victorio
Laboratorio de Compuestos Organometálicos y Catálisis (Unidad Asociada al CSIC), Centro de Innovación en Química Avanzada (ORFEO-CINQA), Departamento de Química Orgánica e Inorgánica, Instituto Universitario de Química Organometálica "Enrique Moles", Facultad de Química, Universidad de Oviedo, Julián Clavería 8, 33006 Oviedo, Spain.
Dalton Trans. 2014 Sep 7;43(33):12447-62. doi: 10.1039/c4dt01494d.
In the last few years there has been increasing interest in the use of water as a reaction medium for catalysis, and therefore in designing water-soluble transition-metal catalysts. Half-sandwich (η(6)-arene)-ruthenium(ii) complexes are a versatile and well-known family of ruthenium compounds that exhibit a rich catalytic and coordination chemistry. This Perspective article focuses on the catalytic applications in aqueous media of (η(6)-arene)-ruthenium(ii) complexes containing water-soluble phosphines, and related hydrophilic P-donor ligands.
在过去几年中，人们对将水用作催化反应介质的兴趣日益浓厚，因此也对设计水溶性过渡金属催化剂产生了兴趣。半夹心（η(6)-芳烃）-钌（II）配合物是一类用途广泛且广为人知的钌化合物，具有丰富的催化和配位化学性质。这篇综述文章重点关注含有水溶性膦以及相关亲水性磷供体配体的（η(6)-芳烃）-钌（II）配合物在水介质中的催化应用。
