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纳米金等离子体光催化在有机合成和清洁能源转化中的应用。

Nanogold plasmonic photocatalysis for organic synthesis and clean energy conversion.

机构信息

ISM, Univ. Bordeaux, 351 Cours de la Libération, 33405 Talence Cedex, France.

出版信息

Chem Soc Rev. 2014;43(20):7188-216. doi: 10.1039/c4cs00145a. Epub 2014 Jul 14.

Abstract

This review provides the basic concepts, an overall survey and the state-of-the art of plasmon-based nanogold photocatalysis using visible light including fundamental understanding and major applications to organic reactions and clean energy-conversion systems. First, the basic concepts of localized surface plasmon resonance (LSPR) are recalled, then the major preparation methods of AuNP-based plasmonic photocatalysts are reviewed. The major part of the review is dedicated to the latest progress in the application of nanogold plasmonic photocatalysis to organic transformations and energy conversions, and the proposed mechanisms are discussed. In conclusion, new challenges and perspectives are proposed and analyzed.

摘要

这篇综述提供了基于等离子体的纳米金光催化利用可见光的基本概念、全面调查和最新进展,包括对有机反应和清洁能源转换系统的基本理解和主要应用。首先,回顾了局域表面等离子体共振(LSPR)的基本概念,然后综述了基于 AuNP 的等离子体光催化剂的主要制备方法。综述的主要部分致力于纳米金等离子体光催化在有机转化和能量转化中的最新进展,并讨论了所提出的机制。最后,提出并分析了新的挑战和展望。

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