基于二茂铁的超分子结构及其在电化学响应系统中的应用。
Ferrocene-based supramolecular structures and their applications in electrochemical responsive systems.
作者信息
Peng Liao, Feng Anchao, Huo Meng, Yuan Jinying
机构信息
Key Lab of Organic Optoelectronics & Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing 100084, China.
出版信息
Chem Commun (Camb). 2014 Nov 7;50(86):13005-14. doi: 10.1039/c4cc05192k.
Electrochemical stimuli have attracted much attention in recent years as they are simple, clean and can be widely applied in biological systems and material science. As one type of common guest molecules, ferrocene and its derivatives have been well studied with different host molecules, mainly including cyclodextrins, cucurbiturils, pillararenes and calixarenes. This article generally summarizes the recent work on the host-guest interactions between ferrocene derivatives and their host molecules, as well as various supramolecular systems based on these interactions. In addition, the development and outlook of electrochemical responsive systems are also discussed.
近年来，电化学刺激因其简单、清洁且能广泛应用于生物系统和材料科学而备受关注。作为一类常见的客体分子，二茂铁及其衍生物已与不同的主体分子进行了深入研究，主要包括环糊精、葫芦脲、柱芳烃和杯芳烃。本文全面总结了二茂铁衍生物与其主体分子之间的主客体相互作用以及基于这些相互作用的各种超分子体系的近期研究工作。此外，还讨论了电化学响应体系的发展与展望。
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