State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, 18 Shuang-qing Road, Beijing, 100085, China.
Environ Sci Pollut Res Int. 2015 Jan;22(2):1232-9. doi: 10.1007/s11356-014-3423-5. Epub 2014 Aug 19.
A total of 86 source water samples from 38 cities across major watersheds of China were collected for a bromide (Br(-)) survey, and the bromate (BrO3 (-)) formation potentials (BFPs) of 41 samples with Br(-) concentration >20 μg L(-1) were evaluated using a batch ozonation reactor. Statistical analyses indicated that higher alkalinity, hardness, and pH of water samples could lead to higher BFPs, with alkalinity as the most important factor. Based on the survey data, a multiple linear regression (MLR) model including three parameters (alkalinity, ozone dose, and total organic carbon (TOC)) was established with a relatively good prediction performance (model selection criterion = 2.01, R (2) = 0.724), using logarithmic transformation of the variables. Furthermore, a contour plot was used to interpret the influence of alkalinity and TOC on BrO3 (-) formation with prediction accuracy as high as 71 %, suggesting that these two parameters, apart from ozone dosage, were the most important ones affecting the BFPs of source waters with Br(-) concentration >20 μg L(-1). The model could be a useful tool for the prediction of the BFPs of source water.
共采集了来自中国主要流域 38 个城市的 86 个水源水样,进行溴化物(Br(-))调查,使用批量臭氧反应器评估了 41 个 Br(-)浓度>20μg/L 的水样的溴酸盐(BrO3(-))形成潜力(BFPs)。统计分析表明,水样的较高碱度、硬度和 pH 值可能导致较高的 BFPs,其中碱度是最重要的因素。根据调查数据,建立了一个包含三个参数(碱度、臭氧剂量和总有机碳(TOC))的多元线性回归(MLR)模型,具有较好的预测性能(模型选择标准=2.01,R(2)=0.724),使用变量的对数转换。此外,使用等高线图来解释碱度和 TOC 对 BrO3(-)形成的影响,预测准确率高达 71%,表明这两个参数除了臭氧剂量外,是影响 Br(-)浓度>20μg/L 的水源 BFPs 的最重要因素。该模型可以成为预测水源 BFPs 的有用工具。