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Synthesis of the C1-C28 Portion of Spongistatin 1 (Altohyrtin A).
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Synthesis of the C-1-C-28 ABCD unit of spongistatin 1.
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Spongipyran Synthetic Studies. Evolution of a Scalable Total Synthesis of (+)-Spongistatin 1.
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Spongipyran Synthetic Studies. Total Synthesis of (+)-Spongistatin 2.
Tetrahedron. 2009 Aug 15;65(33):6470-6488. doi: 10.1016/j.tet.2009.04.001.
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Asymmetric total synthesis of spongistatins 1 and 2.
J Am Chem Soc. 2002 May 22;124(20):5661-3. doi: 10.1021/ja0262683.
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A Highly Stereoselective, Efficient, and Scalable Synthesis of the C(1)-C(9) Fragment of the Epothilones.
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Unusual Enantiodivergence in Chiral Brønsted Acid-Catalyzed Asymmetric Allylation with β-Alkenyl Allylic Boronates.
Angew Chem Int Ed Engl. 2022 Oct 10;61(41):e202208908. doi: 10.1002/anie.202208908. Epub 2022 Sep 6.
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Natural Products in the "Marketplace": Interfacing Synthesis and Biology.
J Am Chem Soc. 2019 Feb 27;141(8):3332-3346. doi: 10.1021/jacs.8b11297. Epub 2019 Feb 13.
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Hydroxyl-directed stereoselective diboration of alkenes.
J Am Chem Soc. 2014 Jul 2;136(26):9264-7. doi: 10.1021/ja504228p. Epub 2014 Jun 24.
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Beyond the Roche ester: a new approach to polypropionate stereotriad synthesis.
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Exploiting pseudo C2-symmetry for an efficient synthesis of the F-ring of the spongistatins.
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A highly step-economical synthesis of dictyostatin.
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1
The Spongistatins: Architecturally Complex Natural Products-Part One: A Formal Synthesis of (+)-Spongistatin 1 by Construction of an Advanced ABCD Fragment.
Angew Chem Int Ed Engl. 2001 Jan 5;40(1):191-195. doi: 10.1002/1521-3773(20010105)40:1<191::AID-ANIE191>3.0.CO;2-C.
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Direct and highly regioselective and enantioselective allylation of β-diketones.
Nature. 2012 Jul 5;487(7405):86-9. doi: 10.1038/nature11189.
4
Design, synthesis, and biological evaluation of diminutive forms of (+)-spongistatin 1: lessons learned.
J Am Chem Soc. 2011 Sep 7;133(35):14042-53. doi: 10.1021/ja2046167. Epub 2011 Aug 12.
5
A more comprehensive and highly practical solution to enantioselective aldehyde crotylation.
J Am Chem Soc. 2011 May 4;133(17):6517-20. doi: 10.1021/ja200712f. Epub 2011 Apr 12.
6
Spongipyran Synthetic Studies. Evolution of a Scalable Total Synthesis of (+)-Spongistatin 1.
Tetrahedron. 2009 Sep 15;65(33):6489-6509. doi: 10.1016/j.tet.2009.04.003.
7
Spongipyran Synthetic Studies. Total Synthesis of (+)-Spongistatin 2.
Tetrahedron. 2009 Aug 15;65(33):6470-6488. doi: 10.1016/j.tet.2009.04.001.
10
Total synthesis of spongistatin 1: a synthetic strategy exploiting its latent pseudo-symmetry.
Angew Chem Int Ed Engl. 2005 Aug 26;44(34):5433-8. doi: 10.1002/anie.200502008.

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