Cyclic ethers to esters and monoesters to bis-esters with unconventional coupling partners under metal free conditions via sp(3) C-H functionalisation.
作者信息
Majji Ganesh, Guin Srimanta, Rout Saroj K, Behera Ahalya, Patel Bhisma K
机构信息
Department of Chemistry, Indian Institute of Technology Guwahati, 781 039, Assam, India.
出版信息
Chem Commun (Camb). 2014 Oct 18;50(81):12193-6. doi: 10.1039/c4cc05050a.
PMID:25177921
Abstract
An efficient metal free oxidative esterification of sp(3) C-H bonds (adjacent to an oxygen atom) in simple solvents like 1,4-dioxane, tetrahydropyran, tetrahydrofuran and ethyl acetate has been achieved using terminal aryl alkenes and alkynes as the ArCOO(-) sources.
摘要
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