Li Guangqin, Kobayashi Hirokazu, Kusada Kohei, Taylor Jared M, Kubota Yoshiki, Kato Kenichi, Takata Masaki, Yamamoto Tomokazu, Matsumura Syo, Kitagawa Hiroshi
Division of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa-Oiwakecho, Sakyo-ku, Kyoto 606-8502, Japan.
Chem Commun (Camb). 2014 Nov 18;50(89):13750-3. doi: 10.1039/c4cc05941g.
Presented here is the synthesis of an ordered bcc copper-palladium nanoalloy, via the decomposition of a Pd nanoparticle@metal-organic framework composite material. In situ XRD measurements were performed in order to understand the mechanism of the decomposition process. This result gives a further perspective into the synthesis of new nanomaterials via metal-organic framework decomposition.
本文展示了通过钯纳米颗粒@金属有机框架复合材料的分解来合成有序体心立方铜钯纳米合金。进行原位X射线衍射测量以了解分解过程的机制。这一结果为通过金属有机框架分解合成新型纳米材料提供了进一步的视角。