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基于N-十六烷基-N-甲基哌啶溴化物的阳离子表面活性剂与阴离子表面活性剂形成的蠕虫状胶束的形成及溶液性质研究。

Study of the formation and solution properties of worm-like micelles formed using both N-hexadecyl-N-methylpiperidinium bromide-based cationic surfactant and anionic surfactant.

作者信息

Yan Zhihu, Dai Caili, Feng Haishun, Liu Yifei, Wang Shilu

机构信息

School of Petroleum Engineering, China University of Petroleum (Huadong), Qingdao, P. R. China.

出版信息

PLoS One. 2014 Oct 8;9(10):e110155. doi: 10.1371/journal.pone.0110155. eCollection 2014.

DOI:10.1371/journal.pone.0110155
PMID:25296131
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC4190405/
Abstract

The viscoelastic properties of worm-like micelles formed by mixing the cationic surfactant N-hexadecyl-N-methylpiperidinium bromide (C16MDB) with the anionic surfactant sodium laurate (SL) in aqueous solutions were investigated using rheological measurements. The effects of sodium laurate and temperature on the worm-like micelles and the mechanism of the observed shear thinning phenomenon and pseudoplastic behavior were systematically investigated. Additionally, cryogenic transmission electron microscopy images further ascertained existence of entangled worm-like micelles.

摘要

通过流变学测量研究了在水溶液中混合阳离子表面活性剂N-十六烷基-N-甲基哌啶溴化物（C16MDB）和阴离子表面活性剂月桂酸钠（SL）形成的蠕虫状胶束的粘弹性特性。系统研究了月桂酸钠和温度对蠕虫状胶束的影响以及观察到的剪切变稀现象和假塑性行为的机制。此外，低温透射电子显微镜图像进一步确定了缠结的蠕虫状胶束的存在。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/22e4/4190405/52ddc9232c82/pone.0110155.g008.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/22e4/4190405/c1ed88b69e84/pone.0110155.g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/22e4/4190405/33b035cb8bbe/pone.0110155.g006.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/22e4/4190405/c1ed88b69e84/pone.0110155.g005.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/22e4/4190405/52ddc9232c82/pone.0110155.g008.jpg

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本文引用的文献

1
Wormlike micelles: where do we stand? Recent developments, linear rheology and scattering techniques.蠕虫状胶束：我们目前的状况如何？近期进展、线性流变学和散射技术。
Soft Matter. 2007 Jul 17;3(8):956-970. doi: 10.1039/b705775j.
2
Micelle formation by N-alkyl-N-methylpyrrolidinium bromide in aqueous solution.N- 烷基-N- 甲基吡咯烷溴在水溶液中形成胶束。
Phys Chem Chem Phys. 2011 Jan 28;13(4):1332-7. doi: 10.1039/c0cp00342e. Epub 2010 Nov 23.
3
Piperidinium, piperazinium and morpholinium ionic liquid crystals.哌啶鎓、哌嗪鎓和吗啉鎓离子液晶。
J Phys Chem B. 2009 Jul 16;113(28):9506-11. doi: 10.1021/jp903667e.
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Novel gel phase formed by mixing a cationic surfactive ionic liquid C(16)mimCl and an anionic surfactant SDS in aqueous solution.通过在水溶液中混合阳离子表面活性离子液体C(16)mimCl和阴离子表面活性剂SDS形成的新型凝胶相。
J Phys Chem B. 2009 Jan 29;113(4):983-8. doi: 10.1021/jp809048u.
5
Self-assembly of nonionic surfactants into lyotropic liquid crystals in ethylammonium nitrate, a room-temperature ionic liquid.非离子表面活性剂在室温离子液体硝酸乙铵中自组装成溶致液晶。
J Phys Chem B. 2005 Aug 4;109(30):14275-7. doi: 10.1021/jp052862y.
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Shear thinning and orientational ordering of wormlike micelles.蠕虫状胶束的剪切变稀和取向有序化
Phys Rev Lett. 2005 Jan 14;94(1):017803. doi: 10.1103/PhysRevLett.94.017803. Epub 2005 Jan 13.
7
Growth and scission energy of wormlike micelles formed by a cationic surfactant with long unsaturated tails.由具有长不饱和尾部的阳离子表面活性剂形成的蠕虫状胶束的生长和断裂能。
Langmuir. 2004 Oct 26;20(22):9541-50. doi: 10.1021/la049046m.