通过有机配体的金属同位素编码分析对复杂基质中的金属载体进行图谱绘制。
Metallophore mapping in complex matrices by metal isotope coded profiling of organic ligands.
作者信息
Deicke Michael, Mohr Jan Frieder, Bellenger Jean-Philippe, Wichard Thomas
机构信息
Friedrich Schiller University Jena, Institute for Inorganic and Analytical Chemistry, Lessingstr. 8, 07743 Jena, Germany.
出版信息
Analyst. 2014 Dec 7;139(23):6096-9. doi: 10.1039/c4an01461h. Epub 2014 Oct 9.
PMID:25298978
Abstract
Metal isotope coded profiling (MICP) introduces a universal discovery platform for metal chelating natural products that act as metallophores, ion buffers or sequestering agents. The detection of cation and oxoanion complexing ligands is facilitated by the identification of unique isotopic signatures created by the application of isotopically pure metals.
摘要
金属同位素编码分析（MICP）为作为金属载体、离子缓冲剂或螯合剂的金属螯合天然产物引入了一个通用的发现平台。通过识别应用同位素纯金属产生的独特同位素特征，有助于检测阳离子和含氧阴离子络合配体。
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