（苯 - 碳 - 硫代酰胺 - κS）二（三苯基膦 - κP）氯化银（I）的晶体结构
Crystal structure of (benzene-carbo-thio-amide-κS)chloridobis-(tri-phenyl-phosphane-κP)silver(I).
作者信息
Ruangwut Wattana, Pakawatchai Chaveng
机构信息
Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112, Thailand.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2014 Aug 1;70(Pt 9):m310-1. doi: 10.1107/S1600536814015992. eCollection 2014 Sep 1.
Abstract
In the mononuclear mixed-ligand title complex, [AgCl(C7H7NS)(C18H15P)2], the Ag(I) ion is four coordinated by one S atom of a benzene-carbo-thio-amide ligand, two P atoms of two tri-phenyl-phosphane ligands and one chloride ion, displaying a distorted tetra-hedral coordination geometry. In the crystal, pairs of N-H⋯Cl hydrogen bonds form inversion dimers. An intra-molecular N-H⋯Cl hydrogen bond is also observed.
摘要
在单核混合配体标题配合物[AgCl(C₇H₇NS)(C₁₈H₁₅P)₂]中，Ag(I)离子由苯甲硫酰胺配体的一个S原子、两个三苯基膦配体的两个P原子和一个氯离子进行四配位，呈现出扭曲的四面体配位几何构型。在晶体中，N—H⋯Cl氢键对形成了反演二聚体。还观察到了分子内的N—H⋯Cl氢键。
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