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基于碳纳米管/聚合物复合材料的正温度系数热敏电阻

Positive temperature coefficient thermistors based on carbon nanotube/polymer composites.

作者信息

Zeng You, Lu Guixia, Wang Han, Du Jinhong, Ying Zhe, Liu Chang

机构信息

Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016, People's Republic of China.

1] School of Materials Science and Engineering, Shandong University, Jinan, Shandong 250061, People's Republic of China [2] School of Materials Science and Engineering, Shenyang Jianzhu University, 9 Hunan East Road, Shenyang 110168, People's Republic of China.

出版信息

Sci Rep. 2014 Oct 20;4:6684. doi: 10.1038/srep06684.

Abstract

In order to explore availability of carbon nanotube (CNT)-based positive temperature coefficient (PTC) thermistors in practical application, we prepared carbon nanotube (CNT) filled high density polyethylene (HDPE) composites by using conventional melt-mixing methods, and investigated their PTC effects in details. The CNT-based thermistors exhibit much larger hold current and higher hold voltage, increasing by 129% in comparison with the commercial carbon black (CB) filled HDPE thermistors. Such high current-bearing and voltage-bearing capacity for the CNT/HDPE thermistors is mainly attributed to high thermal conductivity and heat dissipation of entangled CNT networks. Moreover, the CNT/HDPE thermistors exhibit rapid electrical response to applied voltages, comparable to commercial CB-based thermistors. In light of their high current-bearing capacity and quick response, the CNT-based thermistors have great potential to be used as high-performance thermistors in practical application, especially in some critical circumstances of high temperature, large applied currents, and high applied voltages.

摘要

为了探索基于碳纳米管(CNT)的正温度系数(PTC)热敏电阻在实际应用中的可用性,我们采用传统的熔融混合方法制备了填充碳纳米管(CNT)的高密度聚乙烯(HDPE)复合材料,并详细研究了它们的PTC效应。基于碳纳米管的热敏电阻表现出大得多的保持电流和更高的保持电压,与商用炭黑(CB)填充的HDPE热敏电阻相比增加了129%。碳纳米管/高密度聚乙烯热敏电阻如此高的承载电流和电压能力主要归因于缠结的碳纳米管网络的高导热性和散热性。此外,碳纳米管/高密度聚乙烯热敏电阻对施加电压表现出快速的电响应,与商用炭黑基热敏电阻相当。鉴于其高承载电流能力和快速响应,基于碳纳米管的热敏电阻在实际应用中,特别是在一些高温、大施加电流和高施加电压的关键情况下,具有用作高性能热敏电阻的巨大潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fe50/4202205/c546f8feaf8d/srep06684-f1.jpg

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