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银纳米纤维在湿度、氨气和温度传感中的合成、表征及应用

Synthesis, Characterization, and Applications of Silver Nano Fibers in Humidity, Ammonia, and Temperature Sensing.

作者信息

Rashid Haroon-Ur, Ali Muhammad, Sarker Mahidur R, Md Ali Sawal Hamid, Akhtar Naseem, Khan Nadir Ali, Asif Muhammad, Shah Sahar

机构信息

Department of Electronics, University of Peshawar, Peshawar 25120, Pakistan.

Materials Research Laboratory, Department of Physics, University of Peshawar, Peshawar 25120, Pakistan.

出版信息

Micromachines (Basel). 2021 Jun 10;12(6):682. doi: 10.3390/mi12060682.

Abstract

The promising chemical, mechanical, and electrical properties of silver from nano scale to bulk level make it useful to be used in a variety of applications in the biomedical and electronic fields. Recently, several methods have been proposed and applied for the small-scale and mass production of silver in the form of nanoparticles, nanowires, and nanofibers. In this research, we have proposed a novel method for the fabrication of silver nano fibers (AgNFs) that is environmentally friendly and can be easily deployed for large-scale production. Moreover, the proposed technique is easy for device fabrication in different applications. To validate the properties, the synthesized silver nanofibers have been examined through Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and X-ray diffraction (XRD). Further, the synthesized silver nanofibers have been deposited over sensors for Relative humidity (RH), Ammonia (NH), and temperature sensing applications. The sensor was of a resistive type, and found 4.3 kΩ for relative humidity (RH %) 30-90%, 400 kΩ for NH (40,000 ppm), and 5 MΩ for temperature sensing (69 °C). The durability and speed of the sensor verified through repetitive, response, and recovery tests of the sensor in a humidity and gas chamber. It was observed that the sensor took 13 s to respond, 27 s to measure the maximum value, and took 33 s to regain its minimum value. Furthermore, it was observed that at lower frequencies and higher concentration of NH, the response of the device was excellent. Furthermore, the device has linear and repetitive responses, is cost-effective, and is easy to fabricate.

摘要

从纳米尺度到块状水平,银展现出了令人瞩目的化学、机械和电学性能,这使其在生物医学和电子领域的各种应用中都具有很高的实用价值。最近,人们已经提出并应用了几种方法来小规模和大规模地生产纳米颗粒、纳米线和纳米纤维形式的银。在本研究中,我们提出了一种制备银纳米纤维(AgNFs)的新方法,该方法环保且易于大规模生产。此外,所提出的技术便于在不同应用中制造器件。为了验证其性能,通过傅里叶变换红外光谱(FTIR)、扫描电子显微镜(SEM)和X射线衍射(XRD)对合成的银纳米纤维进行了检测。此外,已将合成的银纳米纤维沉积在用于相对湿度(RH)、氨气(NH)和温度传感应用的传感器上。该传感器为电阻型,在相对湿度(RH%)为30 - 90%时电阻为4.3 kΩ,对于NH(40,000 ppm)为400 kΩ,对于温度传感(69°C)为5 MΩ。通过在湿度和气体腔室中对传感器进行重复、响应和恢复测试,验证了传感器的耐久性和速度。观察到传感器响应时间为13 s,测量最大值时间为27 s,恢复到最小值时间为33 s。此外,观察到在较低频率和较高NH浓度下,该器件的响应非常出色。此外,该器件具有线性和重复响应,具有成本效益且易于制造。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9fca/8230507/b3df690c21d6/micromachines-12-00682-g009.jpg

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