Key Laboratory for Environmentally Friendly Chemistry and Application of the Ministry of Education, College of Chemistry, Xiangtan University, Hunan, 411105, China.
Org Biomol Chem. 2014 Dec 21;12(47):9519-23. doi: 10.1039/c4ob01970a. Epub 2014 Oct 30.
A silver-mediated oxidative vinylic C-H bond sulfenylation of enamides was developed. This method is compatible with diaryl and dialkyl disulfides to deliver biologically precious chalcogenated olefins efficiently. A plausible non-chain radical mechanism was proposed for understanding this novel sulfenylation based on the mechanistic studies.
发展了一种银介导的氧化烯丙基 C-H 键亚磺酰化反应。该方法与二芳基和二烷基二硫化物兼容，可有效地提供生物上重要的含硫烯烃。通过机理研究，提出了一种合理的非链式自由基机理来理解这种新的亚磺酰化反应。
