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面向边缘的 MoS2 纳米多孔薄膜作为用于析氢反应和超级电容器器件的柔性电极。

Edge-oriented MoS2 nanoporous films as flexible electrodes for hydrogen evolution reactions and supercapacitor devices.

机构信息

Department of Chemistry, Rice University, 6100 Main Street, Houston, Texas, 77005, USA; Smalley Institute for Nanoscale Science and Technology, Rice University, 6100 Main Street, Houston, Texas, 77005, USA.

出版信息

Adv Mater. 2014 Dec 23;26(48):8163-8. doi: 10.1002/adma.201402847. Epub 2014 Oct 29.

Abstract

A simple method to fabricate edge-oriented MoS2 films with sponge-like morphologies is demonstrated. They are directly fabricated through the reaction of sulfur vapor with anodically formed Mo oxide sponge-like films on flexible Mo substrates. The edge-oriented MoS2 film delivers excellent hydrogen evolution reaction (HER) activity with enhanced kinetics and long-term cycling stability. The material also has superior energy-storage performance when working as a flexible, all-solid-state supercapacitor device.

摘要

本文展示了一种简单的方法来制备具有海绵状形态的边缘取向的 MoS2 薄膜。它们是通过将硫蒸气与在柔性 Mo 基底上形成的阳极氧化 Mo 氧化物海绵状薄膜反应直接制备的。边缘取向的 MoS2 薄膜具有出色的析氢反应 (HER) 活性,具有增强的动力学和长期循环稳定性。当用作柔性全固态超级电容器器件时,该材料还具有优异的储能性能。

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