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增强电催化析氢：调控二硫化钼中的不饱和电子结构

Enhancing electrocatalytic hydrogen evolution engineering unsaturated electronic structures in MoS.

作者信息

Zhou Qingqing, Hu Hao, Chen Zhijie, Ren Xiao, Ma Ding

机构信息

Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking University Beijing 100871 China

College of Environment, Zhejiang University of Technology Hangzhou 310012 PR China.

出版信息

Chem Sci. 2024 Dec 18;16(4):1597-1616. doi: 10.1039/d4sc07309f. eCollection 2025 Jan 22.

DOI:10.1039/d4sc07309f
PMID:39776652
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11701923/
Abstract

The search for efficient, earth-abundant electrocatalysts for the hydrogen evolution reaction (HER) has identified unsaturated molybdenum disulfide (MoS) as a leading candidate. This review synthesises recent advancements in the engineering of MoS to enhance its electrocatalytic properties. It focuses on strategies for designing an unsaturated electronic structure on metal catalytic centers and their role in boosting the efficiency of the hydrogen evolution reaction (HER). It also considers how to optimize the electronic structures of unsaturated MoS for enhanced catalytic performance. This review commences with an examination of the fundamental crystal structure of MoS; it elucidates the classical unsaturated electron configurations and the intrinsic factors that contribute to such electronic structures. Furthermore, it introduces popular strategies for constructing unsaturated electronic structures at the atomic level, such as nanostructure engineering, surface chemical modification and interlayer coupling engineering. It also discusses the challenges and future research directions in the study of MoS electronic structures, with the aim of broadening their application in sustainable hydrogen production.

摘要

寻找用于析氢反应（HER）的高效、地球上储量丰富的电催化剂已确定不饱和二硫化钼（MoS）为主要候选材料。本综述总结了MoS工程方面的最新进展，以增强其电催化性能。它侧重于在金属催化中心设计不饱和电子结构的策略及其在提高析氢反应（HER）效率中的作用。它还考虑了如何优化不饱和MoS的电子结构以增强催化性能。本综述首先考察了MoS的基本晶体结构；阐明了经典的不饱和电子构型以及促成此类电子结构的内在因素。此外，还介绍了在原子水平构建不饱和电子结构的常用策略，如纳米结构工程、表面化学修饰和层间耦合工程。它还讨论了MoS电子结构研究中的挑战和未来研究方向，旨在拓宽其在可持续制氢中的应用。

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