氨基糖的化学选择性全-O-三甲基硅基化和均相N-官能化
Chemoselective per-O-trimethylsilylation and homogeneous N-functionalisation of amino sugars.
作者信息
Joseph A Abragam, Dhurandhare Vijay M, Chang Chun-Wei, Verma Ved Prakash, Mishra Girija Prasad, Ku Chiao-Chu, Lin Chun-Cheng, Wang Cheng-Chung
机构信息
Institute of Chemistry, Academia Sinica, Taipei 115, Taiwan.
出版信息
Chem Commun (Camb). 2015 Jan 4;51(1):104-6. doi: 10.1039/c4cc06645f.
PMID:25384128
Abstract
A highly efficient CH3CN-promoted hexamethyldisilazane per-O-trimethylsilylation of amino sugars was developed. Its applications in homogenous N-functionalisation and a concise synthesis of glucosamine 6-phosphate are described.
摘要
开发了一种高效的由乙腈促进的氨基糖全-O-三甲基硅烷基化反应，该反应使用六甲基二硅氮烷。描述了其在均相N-官能化中的应用以及6-磷酸葡萄糖胺的简洁合成。
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