Aspetti Carlos O, Agarwal Ritesh
Department of Materials Science and Engineering, University of Pennsylvania , Philadelphia, Pennsylvania 19104, United States.
J Phys Chem Lett. 2014 Nov 6;5(21):3768-3780. doi: 10.1021/jz501823d. Epub 2014 Oct 10.
Semiconductor nanowires, due to their unique electronic, optical, and chemical properties, are firmly placed at the forefront of nanotechnology research. The rich physics of semiconductor nanowire optics arises due to the enhanced light-matter interactions at the nanoscale and coupling of optical modes to electronic resonances. Furthermore, confinement of light can be taken to new extremes via coupling to the surface plasmon modes of metal nanostructures integrated with nanowires, leading to interesting physical phenomena. This Perspective will examine how the optical properties of semiconductor nanowires can be altered via their integration with highly confined plasmonic nanocavities that have resulted in properties such as orders of magnitude faster and more efficient light emission and lasing. The use of plasmonic nanocavities for tailored optical absorption will also be discussed in order to understand and engineer fundamental optical properties of these hybrid systems along with their potential for novel applications, which may not be possible with purely dielectric cavities.
半导体纳米线因其独特的电学、光学和化学性质,稳固地处于纳米技术研究的前沿。半导体纳米线光学丰富的物理现象源于纳米尺度上增强的光与物质相互作用以及光学模式与电子共振的耦合。此外,通过与与纳米线集成的金属纳米结构的表面等离子体模式耦合,光的限制可以达到新的极致,从而导致有趣的物理现象。本观点将探讨如何通过将半导体纳米线与高度受限的等离子体纳米腔集成来改变其光学性质,这种集成已产生了诸如快几个数量级且更高效的光发射和激光发射等性质。还将讨论使用等离子体纳米腔进行定制光学吸收,以便理解和设计这些混合系统的基本光学性质及其在新型应用中的潜力,而这对于纯介质腔可能是无法实现的。