钯/降冰片烯化学：通过在单个合成序列中形成三个Csp3-Csp2/Csp3-N/Csp2-N键生成甲咔唑衍生物的意外途径。
Palladium/norbornene chemistry: an unexpected route to methanocarbazole derivatives via three Csp3-Csp2/Csp3-N/Csp2-N bond formations in a single synthetic sequence.
作者信息
Jafarpour Farnaz, Jalalimanesh Nafiseh, Teimouri Mahdieh, Shamsianpour Mitra
机构信息
School of Chemistry, College of Science, University of Tehran, P.O. Box 14155-6455, Tehran, Iran.
出版信息
Chem Commun (Camb). 2015 Jan 4;51(1):225-8. doi: 10.1039/c4cc06789d.
PMID:25408204
Abstract
A Catellani reaction terminated by palladacycle amination leading to methanocarbazoles is reported. The outcome is the formation of three different Csp(3)-Csp(2)/Csp(3)-N/Csp(2)-N bonds through a Heck reaction/C-H activation/double amination cascade in one process.
摘要
报道了一种通过钯环胺化终止的卡泰拉尼反应，该反应生成了甲氧基咔唑。其结果是在一个过程中通过Heck反应/C-H活化/双胺化级联形成了三种不同的Csp(3)-Csp(2)/Csp(3)-N/Csp(2)-N键。
Zotero 插件